The manufacturing of high-purity semiconductor grade polysilicon begins with the raw material, metallic silicon, of greater than 98% purity. The metallic siliconis reacted with hydrogen chloride gas (HCI) in a fluidized bed reactor, producing trichlorosilane gas (TCS) and a side stream product, silicon tetrachloride (STC). The STC is sent to a co-product sharing customer. The trichlorosilane gas is cooled in a chain of low-temperature heat exchangers and liquefied. Impurities with higher or lower boiling points than the trichlorosilane liquid - such as iron, boron, phosphorous and aluminum compounds - are then removed in a series of distillation columns. The refined trichlorosilane is stored in tanks and tested for chemical and physical performance before further processing.
Serving A Global Market
The Information Age, as the second half of the twentieth century
has come to be known, has been witness to an explosive growth in
technology - personal computers, communications equipment,
consumer electronics and sophisticated diagnostic tools. This "information technology" impacts every facet of contemporary life.
Indeed, it is the engine that drives the global economy. Because of
the extraordinary precision and quality required of semiconductors,
the material of which they are made must be equally extraordinary.
Process
REDUCTION
Once it has been analyzed, the trichlorosilane liquid is vaporized, mixed with hydrogen gas and sent to a reduction or Chemical Vapor
Deposition (CVD) furnace. During the chemical vapor deposition process, silicon from the gas stream is deposited on the surface of
electrically heated polysilicon seed rods. The reduction furnace is precisely controlled to grow the polysilicon rod to a predetermined
diameter. Exhaust gases which are released during this process are cooled, liquefied and distilled, yielding the co-products silicon
tetrachloride (STC) which is marketed separately and trichlorosilane which is recycled.
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